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Y Zeolite Catalyst

Y zeolite (FAU framework) is the foundational large-pore zeolite in industrial catalysis — the parent material from which HY and USY zeolites are derived. Its 12-membered ring openings (~7.4 Å) open into internal supercages approximately 12 Å in diameter, providing the molecular space needed to crack heavy hydrocarbon molecules and accommodate bulky reaction intermediates.

In its sodium form (Na-Y), Y zeolite is the starting point for two of the most important industrial catalyst families: HY zeolite (proton-exchanged for strong Brønsted acidity) and USY zeolite (dealuminated for hydrothermal stability and mesoporosity). Together, these derivatives power the global FCC catalyst market and form the backbone of zeolite-based hydrocracking.

Na-Y is also used directly in ion-exchange applications, as a catalyst support, and in adsorption and separation processes where its large-pore capacity and cation-exchange properties are valuable. We supply Na-Y with SiO₂/Al₂O₃ ratios from 2.5 to 6+ and sodium content from 2 to 13 wt%.

How to Select the Right Y Zeolite Grade

Most buyers select Y zeolite based on what they plan to make from it.

Na-Y vs derived forms. Na-Y is the ion-exchange precursor and adsorption-grade material. It is not acidic. If you need acid catalysis, you will typically convert Na-Y to HY (via NH₄⁺ exchange and calcination) or to USY (via steam dealumination). We supply Na-Y as the starting powder; HY and USY are also available as finished products.

SiO₂/Al₂O₃ ratio determines the acid site density after conversion. Lower SAR (2.5-4) provides the highest potential acidity — important when you are making HY for fine-chemical acid catalysis. Medium SAR (5-6) is the typical FCC precursor range and balances ion-exchange capacity with structural integrity during subsequent dealumination.

Sodium content matters for catalyst manufacturing. Na-Y naturally contains 2-13 wt% Na₂O. If you are converting to HY or USY, the sodium must be reduced below 0.1 wt% to activate Brønsted acidity. We supply Na-Y at the sodium level you specify, and can provide pre-exchanged NH₄-Y as an intermediate.

Crystallinity and phase purity affect downstream performance. High-crystallinity Na-Y (≥90% XRD) produces higher-quality HY and USY after conversion. Specify your minimum crystallinity requirement when ordering precursor-grade Na-Y.

Available Y Zeolite Grades

GradeSiO₂/Al₂O₃ (molar)Na₂O (wt%)FormRecommended For
Na-Y-43.5-4.57-13%PowderFCC precursor, ion exchange, adsorption
Na-Y-65-62-7%PowderFCC and hydrocracking precursor, higher framework SAR
NH₄-Y3.5-6≤0.1%PowderDirect conversion to HY zeolite
HY3.5-12≤0.1%PowderAcid catalysis
USY6-80+≤0.1%Powder or microsphereFCC and hydrocracking

Custom SAR, sodium level, and particle-size grades available. For most catalyst development programs that require acid functionality, start with Na-Y-6 or NH₄-Y and plan your ion-exchange or dealumination route.

Key Specifications

ParameterTypical RangeNotes
FrameworkFAU12-MR channels and ~12 Å supercages
SiO₂/Al₂O₃ (molar)2.5-6 (Na-Y); 3.5-80+ (HY/USY)Fundamental limit: FAU cannot be synthesised below SAR ~2.5
BET surface area600-800 m²/gAmong the highest of commercial zeolites
Pore size~7.4 Å (12-MR windows)Large-pore access to supercages
Supercage diameter~12 ÅAccommodates multi-ring aromatics and heavy hydrocarbons
Unit cell size24.50-24.70 Å (Na-Y)Decreases during dealumination to HY/USY
Na₂O content2-13 wt% (Na-Y); ≤0.1 wt% (HY/USY)High Na₂O blocks acidity; must be reduced for acid catalysis
Particle size0.5-5 μm (powder)Custom ranges available
XRD crystallinity≥90%FAU reference

COA data for every shipment can include SiO₂/Al₂O₃ ratio, Na₂O content, BET surface area, unit cell size, particle size distribution, LOI, and XRD crystallinity.

FCC and Hydrocracking: The Derivative Pathway

Y zeolite is not used directly as an FCC cracking catalyst — its sodium form has no Brønsted acidity and would collapse in an FCC regenerator. Instead, Na-Y is converted to USY through ammonium exchange and steam dealumination, producing the stable, acidic material that dominates FCC catalysts worldwide. The quality of the starting Na-Y — its crystallinity, SAR, and sodium distribution — directly affects the quality of the resulting USY.

The same pathway applies to hydrocracking. Na-Y is the precursor, USY is the working catalyst. Catalyst developers who formulate their own FCC or hydrocracking catalysts often prefer to start from Na-Y and control the dealumination and metal-loading steps themselves.

For application-level guidance, see the FCC solution hub and the USY product page.

Ion Exchange, Adsorption, and Alkylation

Na-Y’s high cation-exchange capacity and large-pore FAU structure make it useful in applications beyond cracking. It is used as an ion-exchange material for water treatment and metal recovery, as a desiccant and adsorbent in gas drying and purification, and as a catalyst support where the large supercages accommodate metal clusters or complexes.

In alkylation, HY zeolite (derived from Na-Y) provides strong solid acidity for ethylbenzene, cumene, and other aromatic alkylation reactions. Na-Y itself can serve as the starting material for custom metal-exchanged alkylation catalysts.

Relationship to HY and USY

Y zeolite is best understood as the platform. HY is the acidic derivative — maximum Brønsted acidity, suitable for reactions where hydrothermal stability is not the limiting factor. USY is the stable derivative — the workhorse of FCC and hydrocracking where steam and high temperature demand framework resilience.

For decision guidance between the derivatives, see HY vs USY. For comparison against other frameworks, see ZSM-5 vs Y Zeolite and Beta vs Y Zeolite.

Technical Documents

Download the Y Zeolite TDS for SiO₂/Al₂O₃, BET surface area, Na₂O, unit cell size, particle size, and XRD data.

When requesting a sample, specify whether you need Na-Y precursor, NH₄-Y intermediate, or finished HY/USY, and provide your target SAR range and sodium level.

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