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Application Note: ZSM-5 for FCC Additives

ZSM-5 is the most widely used FCC additive for propylene enhancement and gasoline octane improvement.

GradeSi/Al (molar)FormBest For
ZSM-5-2520–30H-form powderMaximum propylene response, high acidity
ZSM-5-5040–60H-form powderBalanced activity and stability
P-ZSM-5As specifiedPhosphorus-stabilizedUnits with severe hydrothermal conditions

How It Works

ZSM-5’s 10-MR channels selectively crack low-octane linear C₇–C₁₂ olefins in the gasoline boiling range to C₃–C₅ olefins. Branched and cyclic hydrocarbons cannot enter the pores, so high-octane gasoline components are preserved. Propylene yield increases by 2–6 percentage points and gasoline research octane rises by 1–3 numbers, with minimal impact on conversion or coke at typical loadings of 2–10 wt%.

Specifying a Sample

Provide your current FCC catalyst system, target propylene increase, regenerator temperature, and whether phosphorus stabilization is required. See ZSM-5 for FCC Additives for operating data and the ZSM-5 TDS for batch specifications.

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